You may use Gauss's law to find that the electric field at the surface of each sphere is E=k*q/r2, where k is the coulomb constant, q is the charge on the sphere and r is its radius. The electric potential on the surface of each sphere is found by integrating the work done in moving a unit charge in from infinity. This gives us V=k*q/r for each sphere.
The ratio of the charges then will be q1/q2=r2/r1=2/1. The total charge is 10-2 or 8 Coulombs. q1=2q2 and q1+q2=8. Solve for q1 and q2.
This information is brought to you by M. Casco Associates, a company dedicated to helping humankind reach the stars through understanding how the universe works. My name is James D. Jones. If I can be of more help, please let me know. JDJ